The Three-Stage Deposition Process for Producing Cu(In,Ga)Se2 Thin Films and How Sodium Affects Their Characterization

Authors
  • CJSung

    English

    Author

  • Chen GC

    English

    Author

Keywords:
Cu(In,Ga)Se2, Three-stage Deposition Process;
Abstract

This study aims to compare Mo/SLG to Cu(In,Ga)Se2 (CIGS) thin films made using a three-stage deposition technique with a MoNa back
contact and determine the effect of sodium on their properties. Unlike CIGS deposited into Na-free substrates, which have the (220/204)
preferred orientation, all CIGS thin films placed onto Mo/SLG substrates have the (112) preferred orientation, according to the XRD data.
Because sodium has a surfactant effect that may lower the surface free energy during development, the (220/204) orientation becomes
increasingly frequent in CIGS thin films as the MoNa thickness grows. Increasing the Na concentration causes the grain size near the back
contact to shrink and the Ga gradient to become greater. Raman spectroscopy shows that, in the absence of an OVC chemical, each of the
CIGS thin films displays a single peak. 

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Published
2025-05-10
Section
Articles